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　　分類: 图书,自然科学,化学,有机化学,

作者： （英）卡如萨 著

出 版 社： 世界图书出版公司

出版时间： 2008-10-1字数：版次： 1页数： 493印刷时间：开本： 16开印次：纸张：I S B N ： 9787506292702包装： 平装编辑推荐

作者简介：BILL CARRUTHERS was born in Glasgow. He won a bursary to Glasgow Uni-

versity, where he graduated with a first-class honours degree in 1946 and a Ph.D.

in 1949. He moved to Exeter in 1956, working first for the Medical Research

Council and then, from 1968, as a lecturer then senior lecturer at the Department

of Chemistry in the University of Exeter. He died in April 1990, just a few months

before he was due to retire.

内容简介

The fourth edition of this well-known textbook discusses the key methods used in

organic synthesis, showing the value and scope of these methods and how they are

used in the synthesis of complex molecules. All the text from the third edition has

been revised, to produce a modem account of traditional methods and an up-to-date

description of recent advancements in synthetic chemistry. The textbook maintains

a traditional and logical approach in detailing carbon--carbon bond formations,

followed by a new chapter on the functionalization of alkenes and concluding with

oxidation and reduction reactions. Reference style has been improved to include

footnotes, allowing easy and rapid access to the primary literature. In addition, a

selection of problems has been added at the end of each chapter, with answers

at the end of the book. The book will be of significant interest to chemistry and

biochemistry students at advanced undergraduate and graduate level, as well as

to researchers in academia and industry who wish to familiarize themselves with

modem synthetic methods.

目录

Preface to the first edition

Preface to the fourth edition

1 Formation of carbon-carbon single bonds

1.1 Main-group chemistry

1.1.1 Alkylation of enolates and enamines

1.1.2 Conjugate addition reactions of enolates and enamines

1.1.3 The aldol reaction

1.1.4 Asymmetric methodology with enolates and enamines

1.1.5 Organolithium reagents

1.1.6 Organomagnesium reagents

1.1.7 Organozinc reagents

1.1.8 Allylic organometallics of boron, silicon and tin

1.2 Transition-metal chemistry

Problems

1.2.1 Organocopper reagents

1.2.2 Organochromium chemistry

1.2.3 Organocobalt chemistry

1.2.4 Organopalladium chemistry

2 Formation of carbon-carbon double bonds

2.1 B-Elimination reactions

2.2 Pyrolytic syn eliminations

2.3 Fragmentation reactions

2.4 Alkenes from hydrazones

2.5 Alkenes from 1,2-diols

2.6 Alkenes from alkynes

2.7 The Wittig and related reactions

2.8 Alkenes from sulfones

2.9 Alkenes using titanium or chromium reagents

2.10 Alkene metathesis reactions

Problems

3 Pericyclic reactions

3.1 The Diels-Alder cycloaddition reaction

3.1.1 The dienophile

3.1.2 The diene

3.1.3 Regiochemistry of the Diels-Alder reaction

3.1.4 Stereochemistry of the Diels-Alder reaction

3.1.5 Intramolecular Diels-Alder reactions

3.1.6 The retro Diels-Alder reaction

3.1.7 Asymmetric Diels-Alder reactions

3.2 [2+2] Cycloaddition reactions

3.3 Cycloaddition reactions with allyl cations and allyl anions

3.4 1,3-Dipolar cycloaddition reactions

3.5 The ene reaction

3.6 [3,3]-Sigmatropic rearrangements

3.6.1 The Cope rearrangement

3.6.2 The Claisen rearrangement

3.7 [2,3]-Sigmatropic rearrangements

3.8 Electrocyclic reactions

Problems

4 Radical and carbene chemistry

4.1 Radicals

4.1.1 Radical abstraction reactions

4.1.2 Radical addition reactions

4.2 Carbenes

Problems

5 Functionalization of alkenes

5.1 Hydroboration

5.1.1 Reactions of organoboranes

5.2 Epoxidation and aziridination

5.2.1 Epoxidation

5.2.2 Asymmetric epoxidation

5.2.3 Aziridination

……

6 Oxidation

7 Reduction

Answers to problems

Index

 

 

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