光电子光谱学：原理和应用
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作者： （德）胡夫尼 著
出 版 社： 世界图书出版公司
出版时间： 2009-3-1字数：版次： 1页数： 662印刷时间：开本： 24开印次：纸张：I S B N ： 9787506292771包装： 平装目录
1. Introduction and Basic Principles
1.1 Historical Development
1.2 The Electron Mean Free Path
1.3 Photoelectron Spectroscopy and Inverse Photoelectron Spectroscopy
1.4 Experimental Aspects
1.5 Very High Resolution
1.6 The Theory of Photoemission
1.6.1 Core-Level Photoemission
1.6.2 Valence-State Photoemission
1.6.3 Three-Step and One-Step Considerations
1.7 Deviations from the Simple Theory of Photoemission
References
2. Core Levels and Final States
2.1 Core-Level Binding Energies in Atoms and Molecules
2.1.1 The Equivalent-Core Approximation
2.1.2 Chemical Shifts
2.2 Core-Level Binding Energies in Solids
2.2.1 The Born-Haber Cycle in Insulators
2.2.2 Theory of Binding Energies
2.2.3 Determination of Binding Energies and Chemical Shifts from Thermodynamic Data
2.3 Core Polarization
2.4 Final-State Multiplets in Rare-Earth Valence Bands
2.5 Vibrational Side Bands
2.6 Core Levels of Adsorbed Molecules
2.7 Quantitative Chemical Analysis from Core-Level Intensities
References
3. Charge-Excitation Final States: Satellites
3.1 Copper Dihalides; 3d Transition Metal Compounds
3.1.1 Characterization of a Satellite
3.1.2 Analysis of Charge-Transfer Satellites
3.1.3 Non-local Screening
3.2 The 6-eV Satellite in Nickel
3.2.1 Resonance Photoemission
3.2.2 Satellites in Other Metals
3.3 The Gunnarsson-Sch6nhammer Theory
3.4 Photoemission Signals and Narrow Bands in Metals
References
4. Continuous Satellites and Plasmon Satellites: XPS Photoemission in Nearly Free Electron Systems
4.1 Theory
4.1.1 General
4.1.2 Core-Line Shape
4.1.3 Intrinsic Plasmons
4.1.4 Fxtrinsic FAectron Scattering: Plasmons and Background
411.5 The Total Photoelectron Spectrum
4.2 Experimental Results
4.2.1 The Core Line Without Plasmons
4.2.2 Core-Level Spectra Including Plasmoas
4.2.3 Valence-Band Spectra of the Simple Metals
4.2.4 Simple Metals: A General Comment
4.3 The Background Correction
References
5. Valence Orbitals in Simple Molecules and Insulating Solids
5.1 UPS Spectra of Monatomic Gases
5.2 Photoelectron Spectra of Diatomic Molecules
5.3 Binding Energy of the H2 Molecule
5.4 Hydrides Isoelectronic with Noble Gases
Neon (Ne)
Hydrogen Fluoride (HF)
Water (H2O)
Ammonia (NH3)
Methane (CH4)
5.5 Spectra of the Alkali HMides
5.6 Transition Metal Dihalides
5.7 Hydrocarbons
5.7.1 Guidelines for the Interpretation of Spectra from Free Molecules
5.7.2 Linear Polymers
5.8 Insulating Solids with Valence d Electrons
5.8.1 The NiO Problem
5.8.2 Mort Insulation
……
6. Photoemission of Valence Electrons from Metallic Solids in the One-Electron Approximation
7. Band Structure and Angular-Resolved Photoelectron Spectra
8. Surface States, Surface Effects
9. Inverse Photoelectron Spectroscopy
10. Spin-Polarized Photoelectron Spectroscopy
11. Photoelectron Diffraction
Appendix
Index