解释
參考答案:双季铵盐和钨酸钠催化下双氧水溶液清洁氧化醇和烯烃
Oxidation of alcohols and olefins with hydrogen peroxide using Bis-quaternary ammonium and sodium tungstate
石先莹 刘少恒 汤发有 魏俊发
摘 要：利用三种双季铵盐和钨酸钠催化体系,在无有机溶剂条件下,实现了30%过氧化氢水溶液清洁催化氧化环己醇、苯甲醇、环己烯为环己酮、苯甲醛(苯甲酸)、己二酸;考察了不同催化体系的催化性能.实验结果表明,钨酸钠和双季铵盐催化体系能在温和的条件下,催化稀过氧化氢溶液氧化环己醇、苯甲醇、环己烯.其中,己二酸、苯甲酸、苯甲醛、环己酮的最高产率分别为:74.92%,91.37%,94.51%,82.17%.苯甲醇氧化时,随过氧化氢加入量的不同,可以选择性地给出苯甲醛和苯甲酸.
关键词：催化氧化;双季铵盐;过氧化氢;过钨酸
分类号：O622.31 文献标识码：A
文章编号：1672-4291(2005)01-0078-04
基金项目：国家自然科学基金资助项目(***********);陕西师范大学研究生创新基金资助项目
作者简介：石先莹(1977-),女,陕西户县人,陕西师范大学助教,硕士.魏俊发,通讯联系人:魏俊发,男,陕西师范大学教授,博士.
作者单位：石先莹（陕西师范大学,化学与材料科学学院,陕西,西安,710062）
刘少恒（陕西师范大学,化学与材料科学学院,陕西,西安,710062）
汤发有（陕西师范大学,化学与材料科学学院,陕西,西安,710062）
魏俊发（陕西师范大学,化学与材料科学学院,陕西,西安,710062）
参考文献：
[1]王葆仁.有机合成反应[M].北京:科学出版社,1981.1～102.
[2]Jacobson S E, Muccigrosso D A, Mares F. Oxidation of alcohols by molybdenum and tungsten peroxo complexes [J]. Journal of Organic Chemistry, 1979, 44: 921～924.
[3]Trost M B, Masuyama Y. Chemoselectivity in molybdenum catalyzed alcohol and aldehyde oxidation [J].Tetrahedron Letter, 1984, 25: 173～ 176.
[4]Dengel A C, Griffith W P, Parkin B C. Studies on polyoxo and peroxo-metalates. Part1. Tetrameric heteropolyperoxotungstates and heteropolyperoxomolybdates [J].Journal of Chemical Society Dalton Transaction, 1993,(18) :2 683～2 688.
[5]Neumann R, Gara M. The manganese-containing polyoxometalate [ WZnMn Ⅱ ( ZnW9O34 )2 ]12-, as a remarkably effective catalyst for hydrogen peroxide oxidation [J]. Journal of American Chemical Society,1995, 117:5 066～5 074.
[6]Isbii Y, Yamawaki K, Ura T, et al. Hydrogen peroxide oxidation catalyzed by heteropoly acids combined with cetylpyridinium chloride: epoxidation of olefins and allylic alcohols, ketonizationof alcohols and diols, and oxidative cleavage of 1,2-diols and olefins [J ]. Journal of Organic Chemistry, 1988, 53:3 587～3 593.
[7]Bortolini O, Conte V, Furia F D, et al. Metal catalysis in oxidation by peroxides. Molybdenum and tungstencatalyzed oxidations of alcohols by diluted hydrogen peroxide under phase-transfer conditions [J]. Journal of Organic Chemistry, 1986, 51:2 661～2 663.
[8]Bortolini O, Campestrini S, Furia F D, et al. Matel catalysis in oxidation by peroxides anionic molybdenumpicolinate N-oxido-peroxo complex: an effective oxidation of primary and secondary alcohols in nonpolar solvent [J].Journal of Organic Chemistry, 1987, 52:5 467～5 469.
[9]Zennaro R, Pinna F, Strukul G, et al. A possible molecular pathway for the catalytic oxidation of secondary alcohols to ketones with hydrogen peroxide using Platinum (Ⅱ) complexes as catalysts [J]. Journal of Molecular Catalysis, 1991, 70: 269～275.
[10]Venturello C, Gara M. Selective oxidation of alcohols and aldehydes with hydrogen peroxide catalyzed by methyltrioctylammonium tetrabis ( oxodiperoxotungsto )phosphate(3-) under two phase conditions [J]. Journal of American Chemical Society, 1991, 56:5 924～5 931.
[11]Sato K, Aoki M, Noyori R, et al. Organic solvent, and halide-free oxidation of alcohols with aqueous hydrogen peroxide [J]. Journal of American Chemical Society,1997, 119:12 386～12 387.
[12]Sato K, Aoki M, Takagi J, et al. A practical method for alcohol oxidation with aqueous hydrogen peroxide under organic solvent- and halide-free conditions [J]. Bulletin of Chemical Society Japan, 1999, 72:2 287～2 306.
[13]Sato K, Aoki M, Noyori R. A "green" route to adipic acid: direction oxidation of cyclohexenes with 30%hydrogen peroxide [J]. Science, 1998, 281:1 646～1647.
[14]Iwao T, Yoshiaki K, Jun-ichi I. Lipophilic diammonium cation having a rigid structure complementary to pyrophosphate diunions of nucleotides selective extraction and transport of nucleotides [J]. Journal of American Chemical Society, 1981, 103:6 152～6 157.
[15]Campbell A C, Edwards C D, Griffith P W. Studies on transition metal peroxo complexes. Part 8: the nature of peroxomolybdates and peroxotungstates in aqueous solution [J]. Journal of Chemical Society, Dalton Transaction, 1989, (6): 1 203～1 208.
[16]Dickman M H, Pope M T. Peroxo and superoxo complexes of chromium, molybdenum and tungsten [J].Chemical Review, 1994, 94: 569～584.
[17]Dengel A C, Griffith W P, Powell R D, et al.Asymmetrically coordinated diperoxo compound. Crystal structure of tripotassium oxodiperoxooxalatovanadate (V)monohydrate [J]. Inorganic Chemistry, 1975, 14:1785.
[18]Beiley A J, Griffith W P, Parkin B C. Heteropolyperoxo and isopolyperoxo-tungstates and molybdates as catalysts for the oxidation of tertiary anines, alkenes and alcohols [J]. Journal of Chemical Society, Dalton Transaction,1995, (11): 1 883～1 837.
收稿日期：2003年6月21日
出版日期：2005年3月5日
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