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无机化学(第3版/影印版)Inorganic chemistry

无机化学(第3版/影印版)Inorganic chemistry  点此进入淘宝搜索页搜索
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  分類: 图书,自然科学,化学,无机化学,

作者: (美)米斯勒(Miessler,G.L.),(美)塔尔(Tarr,D.A.)著

出 版 社: 高等教育出版社

出版时间: 2007-11-1字数: 1140000版次: 1页数: 706印刷时间: 2006/12/01开本:印次:纸张: 胶版纸I S B N : 9787040155860包装: 平装目录

PREFACE

1 INTRODUCTION TO INORGANIC CHEMISTRY

1-1 What is Inorganic Chemistry?

1-2 Contrasts with Organic Chemistry

1-3 Genesis of the Elements (The Big Bang)and Flrmation of the Earth

1-4 Nuclear Reactions and Radioactivity

1-5 Distribution of Elements on Earth

1-6 The History of Inorganic Chemistry

2 ATOMIC STRUCTURE

2-1 Historical Development of Atomic Theory

2-1-1 The Periodic Table

2-1-2 Discover of Subatomic Particles and the Bohr Atom

2-2 The Schrodinger Equation

2-2-1 The Particle in a Box

2-2-2 Quantum Numbers and Atomic Wave Functions

2-2-3 The Aufbau Principle

2-2-4 Shielding

2-3 Perildic Properties of Atoms

2-3-1 Ionization Energy

2-3-2 Elecrton Affinity

2-3-3 Covalent and Ionic Radii

3 SIMPLE BONDING THEORY

3-1 Liewis Electron-Dot Diagrams

3-1-1 Resonance

3-1-2 Expanded shells

3-1-3 Formal Charge

3-1-4 Multiple Bonds in Be and B Compounds

3-2 Valence Shell Electron Pair Repulsion Theory

3-2-1 Lone Pair Repulsion

3-2-2 Multiple Bonds

3-2-3 Electroneatuvity and Atomic Size Effects

3-2-4 Ligand Close-Packing

3-3 Polar Molecules

3-4 Hydrogen Bonding

4 SYMMETRY AND GROUP THEORY

4-1 Symmetry Element and Operations

4-2 Point Groups

4-2-1 Groups of Low and High Symmetry

4-2-2 Other Groups

4-3 Properties and Representations of Groups

4-3-1 Matrices

4-3-2 Representations of Point Groups

4-3-3 Character Tables

4-4 Examples and Applications of Symmetry

4-4-1 Chirality

4-4-2 Molecular Vibrations

5 MOLECULAR ORBITALS

5-1 Formation of Molecular Orbiatls form Atomic Orbitals

5-1-1 Molecular Orbitals form s Orbitals

5-1-2 Molecular Orbitals form p Orbitals

5-1-3 Molecular Orbitals form d Orbitals

5-1-4 Nonbonding Orbitals and Other Factors

5-2 Homonuclear Diatomic Molecules

5-2-1 Molecular Orbitals

5-2-2 Orbitals Mixing

5-2-3 First and Second Row Mocecules

5-2-4 Photoelectron Spectroscopy

5-2-5 Correlation Diagrams

5-3 Heteronuclear Diatomic Molecules

5-3-1 Polar Bonds

5-3-2 Ionic Compounds and Molecular Orbiatals

5-4 Molecular Orbitals for Larger Molecules

5-4-1 FHF

5-4-2 CO2

5-4-3 H2O

5-4-4 NH3

5-4-5 BF3

5-4-6 Molecular shapes

5-4-7 Hybrid Orbitals

5-5 Expanded Shells and Molecular Orbitals

6 ACID-BASE AND DONOR-ACCEPTOR CHEMISTRY

6-1 Acid-Base Concepts as Organizing Concepts

6-1-1 History

6-2 Major Acid-Base Concepts

6-2-1 Arrhenius Concept

6-2-2 Brnsted-Lowry Concept

6-2-3 Solvent System Concept

6-2-4 Lewis Concept

6-2-5 Frontier Orbitals and Acid-Base Reactions

6-2-6 Hydrogen Bonding

6-2-7 Electronic Spectra(Including Charge Transfer)

……

7 THE CRYSTALLINE SOLID STATE

8 CHEMISTRY OF THE MAIN GROUP ELEMENTS

9 COORDINATION CHEMISTRYⅠ:STRUSTURES AND ISOMERS

10 COORDINATION CHEMISTRYⅡ:BONDING

11 COORDINATION CHEMISTRYⅢ:ELECTRONIC SPECTRA

12 COORDINATION CHEMISTRYⅣ:REACTIONS AND MECHANISMS

13 ORGANOMETALLIC CHEMISTRY

14 ORGANOMETALLIC REACTONS AND CATALYSIS

15 PARALLELS BETWEEN MAIN GROUP AND ORGANOMETALLIC CHEMISTRY

16 BIOINORGANIC AND ENVIRONMENTAL CHEMISTRY

APPENDIXA ANSWERA TO EXERCISES

APPENDIXA B-1 IONIC RADII

APPENDIXA B-2 IONIZATION ENERGY

APPENDIXA B-3 ELECTORON AFFINITY

APPENDIXA B-4 ELECTRONEGATIVITY

APPENDIXA B-5 ABSOLUTE HARDNESS PARAMETERS

APPENDIXA B-6 CA,EA,CB,AND EB VALUES

APPENDIXA B-7 LATIMER DIAGRAMS FOR SELECTED ELEMENTS

APPENDIXA C CHARACTER TABLES

APPENDIXA ELECTRON-DOT DIAGRAMS AND FORMAL CHARGE

INDEX

 
 
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