现代光谱分析(影印)-生物物理学与生物化学例析
分類: 图书,自然科学,生物科学,生物化学,
作者: (美)帕森(Parson,W.W.)编著
出 版 社: 科学出版社
出版时间: 2008-3-1字数:版次: 1页数: 512印刷时间:开本: 16开印次:纸张:I S B N : 9787030211873包装: 精装内容简介
本书详细论述了光学光谱理论,并介绍如何将这些理论运用于现代分子和细胞生物物理和生物化学。内容包括电子和振动吸收,荧光共振能量转移,激子相互作用,圆二色性,相干和失相,超快泵探针和光子回波光谱,单分子和荧光相关光谱,拉曼散射,以及多重吸收。
本书论述基于时间相关的量子力学,为此领域专业人士提供了足够全面和详细的资料,并例举了数量众多的理论表达式或演示实验等。
本书可供分析化学、生物化学、生物物理学和物理化学等专业高校师生、科研人员参考。
目录
1Introduction
1.1Overview
1.2 The Beer-Lambert Law
1.3Regions of the Electromagnetic Spectrum
1.4Absorption Spectra of Proteins and Nucleic Acids
1.5Absorption Spectra of Mixtures
1.6 The Photoelectric Effect
1.7 Techniques for Measuring Absorbance
1.8Pump-Probe and Photon-Echo Experiments
1.9Linear and Circular Dichroism
1.10 Distortions of Absorption Spectra by Light Scattering or Nonuniform Distributions of the Absorbing Molecules
1.11 Fluorescence
1.12 IR and Raman Spectroscopy
1.13 Lasers
1.14 Nomenclature
2Basic Concepts of Quantum Mechanics
2.1Wavefunctions, Operators, and Expectation Values
2.1.1 Wavefunctions
2.1.2 Operators and Expectation Values
2.2The Time-Dependent and Time-Independent Schr6dinger Equations
2.2.1 Superposition States
2.3Spatial Wavefunctions
2.3.1 A Free Particle
2.3.2 A Particle in a Box
2.3.3 The Harmonic Oscillator
2.3.4 Atomic Orbitals
2.3.5 Molecular Orbitals
2.3.6 Approximate Wavefunctions for Large Systems
2.4Spin Wavefunctions and Singlet and Triplet States
2.5Transitions Between States: Time-Dependent Perturbation Theory
2.6Lifetimes of States and the Uncertainty Principle
3Light
3.1Electromagnetic Fields
3.1.1 Electrostatic Forces and Fields
3.1.2 Electrostatic Potentials
3.1.3 Electromagnetic Radiation
3.1.4 Energy Density and Irradiance
3.1.5 The Complex Electric Susceptibility and Refractive Index.
3.1.6 Local-Field Correction Factors
3.2The Black-Body Radiation Law
3.3Linear and Circular Polarization
3.4 Quantum Theory of Electromagnetic Radiation
3.5Superposition States and Interference Effects in Quantum Optics ..
3.6Distribution of Frequencies in Short Pulses of Light
4Electronic Absorption
4.1Interactions of Electrons with Oscillating Electric Fields
4.2The Rates of Absorption and Stimulated Emission
4.3Transition Dipoles and Dipole Strengths
4.4Calculating Transition Dipoles for rr Molecular Orbitals
4.5Molecular Symmetry and Forbidden and Allowed Transitions
4.6Linear Dichroism
4.7Configuration Interactions
4.8Calculating Electric Transition Dipoles with the Gradient Operator
4.9 Transition Dipoles for Excitations to Singlet and Triplet States
4.10 The Born-Oppenheimer Approximation, Franck-Condon Factors,and the Shapes of Electronic Absorption Bands
4.11 Spectroscopic Hole-Burning
4.12 Effects of the Surroundings on Molecular Transition Energies
4.13 The Electronic Stark Effect
5Fluorescence
5.1The Einstein Coefficients
5.2The Stokes Shift
5.3The Mirror-Image Law
5.4The Strickler-Berg Equation and Other Relationships Between Absorption and Fluorescence
5.5Quantum Theory of Absorption and Emission
5.6Fluorescence Yields and Lifetimes
5.7Fluorescent Probes and Tags
5.8Photobleaching
5.9Fluorescence Anisotropy
5.10 Single-Molecule Fluorescence and High-Resolution Fluorescence Microscopy
5.11 Fluorescence Correlation Spectroscopy
5.12 Intersystem Crossing, Phosphorescence, and Delayed Fluorescence
6 Vibrational Absorption
7 Resonance Energy Transfer
8 Exciton Interactions
9 Circular Dichroism
10 Coherence and Dephasing
11 Pump-Probe Spectroscopy,Photon Echoes,and Vibrational Wavepackets
12 Raman Scattering and Other Multiphoton Processes
Appendix 1-Vectors
Appendix 2-Matrices
Appendix 3-Fourier Transforms
Appendix 4-Fluorescence Phase Shift and Modulation
Appendix 5-CGS and SI Units and Abbreviations
References
Subject Index