基础化学热力学BASIC CHEMICAL THERMODYNAMICS (FIFTH EDITION)
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作者： E. Brian Smith 著
出 版 社： Pengiun Group (USA)
出版时间： 1977-12-1字数：版次： 1页数： 166印刷时间： 2004/01/01开本：印次：纸张： 胶版纸I S B N ： 9781860944468包装： 平装内容简介
This widely acclaimed text, now in its fifth edition and translated into many languages, continues to present a clear, simple and concise introduction to chemical thermodynamics. An examination of equilibrium in the everyday world of mechanical objects provides the starting point for an accessible account of the factors that determine equilibrium in chemical systems. This straightforward approach leads students to a thorough understanding of the basic principles of thermodynamics, which are then applied to a wide range of physico-chemical systems. The book also discusses the problems of non-ideal solutions and the concept of activity, and provides an introduction to the molecular basis of thermodynamics.
Over five editions, the views of teachers of the subject and their students have been incorporated. The result is a little more rigour in specifying the dimensions within logarithmic expressions, the addition of more worked examples and the inclusion of a simple treatment of the molecular basis of thermodynamics. Students on courses in thermodynamics will continue to find this popular book an excellent introductory text.
目录
Notation
1 Introduction
1.1 The scope and nature of chemical thermodynamics
1.2 Equilibrium in mechanical systems
1.3 Reversibility and equilibrium
1.4 Why we need thermodynamics
1.5 The mole
1.6 The perfect gas
2 Energy
2.1 Work
2.2 Heat and temperature
2.3 Measurement of temperature
2.4 Heat and molecular motion
2.5 Conservation of energy
2.6 State functions: a digression
2.7 Enthalpy
2.8 Heat capacity
Problems
3 Entropy and equilibrium
3.1 Reversibility and equilibrium: a recapitulation
3.2 Condition of equilibrium
3.3 Entropy
3.4 Entropy as a state function
3.5 Entropy of expansion of a gas
3.6 Entropy changes accompanying heat flow
3.7 Entropy and equilibrium
3.8 A cosmological aside
3.9 Entropy as a function of pressure and temperature
3.10 Molecular basis of entropy
3.11 Statistical basis of the Second Law
3.12 Magnitudes of entropy changes
3.13 Heat engines
Problems
4 Equilibrium in chemical systems
4.1 Free energy
4.2 Gibbs free energy
4.3 Pressure-dependence of free energy
4.4 Temperature variation of free energy
4.5 Phase equilibria
4.6 Clapeyron equation
4.7 Clausius-Clapeyron equation
4.8 The vapour pressure of liquids
4.9 Chemical potential
4.10 Chemical potential and free energy
4.11 Equilibrium between gaseous reactants
4.12 Temperature-dependence of equilibrium constants
4.13 Effect of pressure on equilibrium constants
4.14 Basic results of chemical thermodynamics
4.15 Le Chatelier's Principle
Problems
5 Determination of thermodynamic quantities
5.1 Hess's Law
5.2 Standard enthalpies of formation
5.3 Average bond energies
5.4 Temperature dependence of enthalpy changes
5.5 Standard free energies of formation
5.6 Determination of free-energy changes
5.7 Determination of entropies of substances
5.8 Example of the determination of thermodynamic quantities
5.9 Calculation of thermodynamic quantities at temperatures otherthan 298 K
5.10 Ellingham diagrams
5.11 Free-energy functions
Problems
6 Ideal solutions
6.1 The ideal solution
6.2 Properties of truly ideal solutions
6.3 Mixtures of liquids
6.4 Ideal solutions of solids in liquids
6.5 Ideal dilute solutions
6.6 Colligative properties
6.7 Freezing-point depression
6.8 Elevation of boiling point
6.9 Osmotic pressure
6.10 Properties of the solute in dilute solutions
6.11 Solubility of solids
Problems
7Non-ideal solutions
8 Thermodynamics of gases
9 Molecular basis of thermodynamics
Answers to Problems
Further reading
Periodic table of elements
Si units and list of physical constants
Index
