Organic Reactions
分類: 图书,进口原版,Professional & Technical(专业与技术类),
品牌: Scott E. Denmark
基本信息出版社:Wiley; Volume 76 (2011年12月20日)丛书名:Organic Reactions精装:584页正文语种:英语ISBN:0470638435条形码:9780470638439商品尺寸:16.2 x 3.4 x 22.8 cm商品重量:885 gASIN:0470638435商品描述内容简介Volume 76 in the venerableOrganic Reactionsseries comprises three chapters that cover the ever-increasing emphasis of transition metal catalysis in organic synthesis. These three chapters represent some of the most important transformations that enable the construction of carbon-carbon bonds, heterocycles and carbon-heteratom bonds. This volume features a comprehensive treatment of transition metal (palladium, nickel, copper) catalyzed a-arylation of enolates derived from many common functional groups such as ketones, aldehydes, esters and nitriles (Prim, Marque, Gaucher, Campagne) including enantioselective variants; palladium catalyzed cyclization to form indoles (Cacchi, Fabrizi, Goggiamani) one of the most prevalent and important classes of heterocycles in natural products and pharmaceutical agents; and an overview of a newly developed dihydroxylation reaction of alkenes (Donohoe, Bataille, Innocenti) that uses hydrogen bonding interactions to direct the delivery of an osmium catalyst with high selectivity. As with allOrganic Reactionschapters, these reviews emphasize the preparative aspects of the featured transformation and contain comprehensive compilations of all known examples in the tables.目录1. HYDROGEN-BONDING-MEDIATED DIRECTED OSMIUM DIHYDROXYLATION
Timothy J. Donohoe, Carole J. R. Bataille, and Paolo Innocenti12. TRANSITION-METAL-CATALYZED α-ARYLATION OF ENOLATES
Damien Prim, Sylvain Marque, Anne Gaucher, and Jean-Marc Campagne 493. INDOLES VIA PALLADIUM-CATALYZED CYCLIZATION
Sandro Cacchi, Giancarlo Fabrizi, and Antonella Goggiamani 281CUMULATIVE CHAPTER TITLES BY VOLUME535AUTHOR INDEX, VOLUMES 1–76 551CHAPTER AND TOPIC INDEX, VOLUMES 1–76 557