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　　分類: 图书,自然科学,化学,无机化学,

作者： 张其锦 著

出 版 社： 中国科学技术大学出版社

出版时间： 2009-1-1字数：版次： 1页数： 197印刷时间：开本： 16开印次：纸张：I S B N ： 9787312022517包装： 平装编辑推荐

本书将具有不同结构的稀土掺杂聚合物作为研究对象，从理论和实验的角度对这些聚合物进行了光谱分析、掺杂基质结构设计、发光性质与各层次结构的关系以及光量子调控等多方面的研究，包括各种新颖结构的设计和由其产生的各种特异性质。

内容简介

聚合物是通过化学键将小分子连接起来而形成的长链状大分子。由这种分子聚集形成的固体材料具有多层次的物质结构，这些结构会影响掺杂其中的各种功能基团的性质。本书将具有不同结构的稀土掺杂聚合物作为研究对象，从理论和实验的角度对这些聚合物进行了光谱分析、掺杂基质结构设计、发光性质与各层次结构的关系以及光量子调控等多方面的研究，包括各种新颖结构的设计和由其产生的各种特异性质。其中光量子调控是迅速发展的宽带通讯领域的关键技术，相应的基础和应用基础研究已形成一个由聚合物科学和光子学交叉而成的新兴学科——光子学聚合物科学。书中介绍的发光调控、三维光学存储和稀土掺杂聚合物光纤的光放大性质等均为光子学聚合物领域的最新进展。虽然本书是非常专业的学术专著，但是通过阅读，读者也能从中了解这一新兴交叉学科的概况。书中还列出了相关原始文献以满足感兴趣的读者进一步了解相关内容的需要。

目录

Chapter 1 Synthesis and characterizationof rare earth complex doped polymers

1.1 Synthesis of rare earth complex doped polymer

1.2 Uniformity and thermal stability of rare earth complex doped polymer

1.2.1 X-ray diffraction of rare earth complex doped

1.2.2 Near-field scanning analysis of rare earth complex doped

1.2.3 Thermal properties of rare earth complex doped PMMA

Chapter 2 Spectroscopic properties of rare earth complex doped PMMA and their Judd-Ofelt treatment

2.1 The theory of spectroscopic analysis

2.1.1 Energy level analysis and nephelauxetic effect of rare earth complexes

2.1.2 Judd-Ofelt Theory

2.2 Spectroscopic analysis of Nd（DBM）3Phen and Nd（DBM）3 （TPPO）2 in PMMA

2.2.1 Energy level analysis and nephelauxetic effect of Nd（DBM）3Phen and Nd（DBM）3 （TPPO）2 in MMA and

2.2.2 Radiative properties of Nd（DBM）3Phen and Nd（DBM）3 （TPPO）2 doped PMMA

2.3 Spectroscopic analysis of Eu complexes in PMMA

2.3.1 Fluorescence of Eu complexes in PMMA

2.3.2 Radiative properties of Eu complexes in PMMA

2.4 Spectroscopic analysis of Er complexes in PMMA

2.4.1 Fluorescence of Er complexes in PMMA

2.4.2 Energy level analysis and nephelauxetic effect of Er（DBM）3 （TPPO）2 in PMMA

2.4.3 Radiative properties of Er（DBM）3 （TPPO）2 doped PMMA

2.5 Spectroscopic analysis of Pr complexes in PMMA

2.5.1 Fluorescence of Pr complexes in PMMA

2.5:2 Energy level analysis and Nephelauxetic effect of

Pr（DBM）3Phen and Pr（DBM）3 （TPPO）2 in PMMA

2.5.3 Radiative properties of Pr（DBM）3 （TPPO）2 doped PMMA

2.6 Spectroscopic analysis of Sm complexes in PMMA

2.6.1 Fluorescent analysis of Sm complexes in MMA

2.6.2 Energy level analysis and nephelauxetic effect of Sm（TTA）a （TPPO）2 in MMA and PMMA

2.6.3 Radiative properties of Sm（DBM）a （TPPO）2 in MMA and PMMA

Chapter 3 Rectification of excitation with bathochromic shift during emission measurement of Eu complexes

3.1 Bathochromic shift during fluorescence measurement

3.2 Theoretical model for treatment of Bathochromic shift

3.3 Prediction of best exciting wavelength for fluorescence measurement

Chapter 4 Fluorescence enhancing of rare earth complexes in PMMA

4.1 Fluorescence enhancement of Eu（DBM）3Phen codoped with the other rare earth complexes in PMMA

4.2 Fluorescence enhancement of Sm（DBM）3Phen codoped with other rare earth complexes in PMMA

4.3 Model for luminescence enhancement in PMMA codoped with two kinds of rare earth complexes

4.3.1 Intra-molecular energy transfer within each complex

4.3.2 Inter-molecular energy transfer between complexes

4.3.3 Quantitative model for luminescence enhancement of Eux Tby-PMMA

Chapter 5 Effects of synergetic ligands on radiative properties of Eu（TTA）3 nL doped PMMA and LB films

5.1

7.1 J-aggregates of rare earth complexes formed on the surface of silver nanoparticles

7.2 Effects of Ag colloidal nanoparticles on luminescent properties of Eu（ l]I） -diketone

7.3 Nanocomposite composed of Eu（TTA）3Bipy/Tb（TTA）3Bipy/Silver Nanoparticles

Chapter 8 Modulation in luminescence of rare earth complexes doped in photo-responsive polymer

8.1 Photo-induced optical anisotropy and polarized emission of europium complex doped azobenzene polymer film

8.2 Reversible modulation in fluorescence intensity of a single vesicle composed of diblock azo-copolymer and Eu （DBM） 3 Phen

Chapter 9 Polymer optical fibers doped with rare earth complexes

9.1 Gradient refractive index distribution of POF

9.1.1 Qualitative description of interfacial-gel polymerization

9.1.2 Diffusion process given by free volume theory

9.1.3 Gradient refractive index distribution of undoped POF~

9.1.4 Gradient refractive index distribution of rare earth complex doped POF

9.2 Design and fabrication of SCPOF preform doped with rare earth complexes

9.3 Optical amplification of rare earth complexes doped SI POF

Postscript

References

 

 

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